X射线荧光光谱法测定燃料中硫各标准的

合并定量限PLOQ、重复性r及其典型值、再现性R及其典


标准

D7212

D7039

D7220

D2622

D4294

ISO20884

对应国内标准

NB/SH/T0842

GB/T11140

GB/T17040

PLOQ

7 mg/kg

3.2 mg ⁄kg

3 mg/kg

3 mg/kg

16.0 mg ⁄kg

5 mg/kg

Type

ALL

ALL

ALL

ALL

Gasoline

Diesel

High Power

ALL

Gasoline

Diesel

ALL

r

1.6196X 0.1

0.4998X0.54

0.6430X 0.504

0.1462X0.8015

0.5006X0.4377

0.1037X0.8000

0.08681X0.8383

0.4347X0.6446

1.6658X0.3300

1.4477X0.3661

1.7+0.0248 X

R

3.7668X 0.1

0.7384X0.54

1.1121X0.504

0.4273X0.8015

1.4533X0.4377

0.3856X0.8000

0.3086X0.8383

1.9182X0.6446

8.9798X0.3300

7.1295X0.3661

1.9+0.1201 X

S, mg/kg

r

R

r

R

r

R

r

R

r

R

r

R

r

R

r

R

r

R

r

R

r

R

1.0

0.09

0.31

3.0

1.1

1.9

0.4

1.1

3.2

0.9

1.4

5.0

1.2

1.8

1.4

2.5

0.5

1.6

1.01

2.94

0.33

1.19

1.8

2.5

8.0

2.0

4.6

10.0

2.0

4.7

1.7

2.6

2.1

3.5

0.9

2.7

1.37

3.98

0.60

2.13

1.9

3.1

11.0

0.71

2.63

15.0

2.1

4.9

2.2

3.2

16.0

2.6

11

20.0

2.2

5.1

25.0

2.2

5.2

2.8

4.2

3.3

5.6

1.9

5.6

2.05

5.95

1.36

5.06

1.28

4.58

3.4

15

4.8

26

3.3

5.6

50.0

4.1

6.1

4.6

8.0

3.4

9.8

2.31

8.20

5.4

24

6.0

30

4.6

8.0

70.0

3.21

9.33

100

6

9

6.5

11.3

5.9

17.1

4.13

15.35

4.12

14.66

8.5

37

7.6

41

7.8

38

6.5

11.3

250

10

15

10.4

18.0

10.4

18.0

500

14

21

14.7

25.2

21

62

15.0

55.6

15.9

56.5

24

105

13

70

14

69

14.7

25.2

942

20.3

35.1

1000

21

31

37

108

26.0

96.9

28.4

101.0

37

165

16

88

18

89

2000

30

45

2822

36

54

5000

135

394

109.5

389.3

105

465

5500

102

379

29

154

34

167

10000

235

687

196

696

165

727

46000

798

2333

704

2501

440

1943